What is the main protocol difference between The libelium mesh protocol and Digimesh protocol.

I am not sure I can answer that as I have never heard of the Libelium mesh. What I can tell you is what I know about the Digi Mesh protocol.

The Digi Mesh protocol is a true peer to peer protocol unlike the Zigbee mesh. That is to say, providing you have the same channel and PAN ID, you can send data to any node within a network via other nodes which are acting as routers. (In most cases, all nodes in a Digi Mesh network are routers), however, you do have options that can change that in a Digi Mesh network that will allow you to configure nodes as sleeping routers or sleeping end devices.

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Hello, you can read about it here:

http://sensor-networks.org/index.php?page=0823123150

This is an useful link about the XBee ZB Digi module in Waspmote, I hope it helps.

Thanks, regards.