Hi, can we use this kit for establishing both star and mesh (and probably cluster) topology via xctu and micropython ?
Sure you can. That is just a matter of the addressing set up and if routing is needed to reach the destination or not.
Any example?
I don’t have an explicit example. But perhaps this would help you understand the addressing more:
https://www.digi.com/support/knowledge-base/xbee-802-15-4-addressing