I am searching for any methods to configure XBee’s completely through command line in Rpi without any UI. Please suggest me some methods by which I can achieve my requirement.
If any links available please mail to firstname.lastname@example.org
Have you read over the command mode section of the manual? Any command you can issue via a web UI such as XCTU can be done by direct access to the UART and AT command mode.
ATID3, WR, CN
It is as simple as that.