XBee Series 2 coordinator sampling

A straightforward question, but can’t find a definitive answer.
I have a small network of XBee Series 2 modules with coordinator, a couple of routers and a couple of end devices.
Can the coordinator be set up to periodically take analogue or digital samples?
I tried a spare module set up as coordinator on its own in XCTU, but nothing happening in API or AT mode. I have set a couple of digital inputs and a sampling rate of 10-seconds.
The manual has digital input etc. as available in CRE (Coordinator etc.), so I can’t see why it shouldn’t work, but I have my doubts.