The Temp measurement cluster ID is NOT directly supported by the XBee and its Application. You need to use the API interface and have your external processor support that cluster ID if you want it supported.
The S2C supports the HA profile to the extent that an RF radio need to support it. That is, it supports Association and the RF side of things. Your application that you write and load on an external processor needs to support the rest of the profile and functions.
You need to look over the API section of the XBee S2C ZB product manual to see what API frames are supported. I would also suggest looking over the supported ZDO commands or functions listing in the manual as well.